Synthesis p. 1215 - 1217 (1993)
Update date:2022-08-05
Topics:
Makosza
Kinowski
Ostrowski
Reaction of nitroarenes with phenylthiomethyl isocyanide in the presence of potassium tert-butoxide results in the introduction of the isocyanomethyl substituent into positions ortho or para to the nitro group. The products of the reaction when subjected to mild hydrolysis can be converted into nitrobenzylic amines or their formyl derivatives.
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