Journal of Organic Chemistry p. 3533 - 3537 (1981)
Update date:2022-07-31
Topics:
Olah, George A.
Fung, Alexander P.
Narang, Subhash C.
Olah, Judith A.
Benzene, alkylbenzenes, halobenzenes, and anisole were nitrated with silver nitrate/boron trifluoride in acetonitrile solution.Correlation of competitive rates with ?- and ?-complex stabilities indicated that the transition state of highest energy lies relatively early on the reaction coordinate.Data indicate that nitrations occur via a polarized complex of the nitrating agent, with the catalyst undergoing nucleophilic displacement by the aromatic substrate.
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