Chemistry Letters p. 359 - 362 (1991)
Update date:2022-08-05
Topics:
Sakakura, Toshiyasu
Tanaka, Masato
Dehydrogenation of cycloalkanes to cycloalkenes is catalyzed by RhCl(CH2=CH2)(PMe3)2 under ethylene pressure at a high temperature over 170 deg C.Ethylene insertion into sp3 C-H bond of cycloalkanes occurs at 230 deg C to afford ethylcycloalkanes.
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