Inorganic Chemistry p. 457 - 461 (1966)
Update date:2022-08-05
Topics:
Magnelli
Tesi
Lowe Jr.
Mcquistion
Bis(pentafluorophenyl)chlorophosphine and pentafluorophenyldichlorophosphine are prepared in good yields from pentafluorophenylmagnesium bromide and phosphorus trichloride. The reactions of the halophosphines with the Lewis bases water, ammonia, dimethylamine, and 2-methylaziridine produced substituted phosphines. Oxidative chlorination of bis(pentafluorophenyl)phosphinamide followed by dehydrohalogenation gave perfluorophenylphosphonitriles. The infrared and pertinent proton magnetic resonance spectra of these compounds are discussed.
View MoreContact:+86 512 6287 2180
Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Contact:0792-8228321
Address:10TH Floor No.121 binjiang Road Xunyang District
NingBO Hong Xiang Biochem.Co.Ltd
website:http://www.hxbiochem.com
Contact:0574-66003444
Address:Ning Bo Bei Lun
Shanghai Egoal Chemical Co.,Ltd
Contact:+86-21-50333091
Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
website:http://www.debyesci.com
Contact:+85221376140
Address:Rm. 19C, Lockhart Ctr., 301-307 Lockhart Rd., Wan Chai
Doi:10.1016/S0022-328X(01)01167-6
(2001)Doi:10.1016/j.catcom.2016.11.015
(2017)Doi:10.1016/S0020-1693(02)01133-7
(2002)Doi:10.1039/c39900000189
(1990)Doi:10.1007/BF00764627
(1990)Doi:10.1016/j.jorganchem.2010.10.041
(2011)