Journal of Organic Chemistry p. 966 - 969 (2002)
Update date:2022-08-04
Topics:
Nishino, Toshiki
Watanabe, Toshihisa
Okada, Mitsuo
Nishiyama, Yutaka
Sonoda, Noboru
Results of the reaction of alkyl halides with lanthanum metal have been shown. The reduction of alkyl iodide with 1/3 equiv of lanthanum metal efficiently proceeded to give the corresponding reductive dimerized products along with the formation of reduction and dehydroiodination products. In the case of alkyl bromides and chlorides, the reaction did not proceed under the same reaction conditions as that of alkyl iodides; however, the reaction was dramatically promoted by the addition of a catalytic amount of iodine. A reaction pathway including alkyl radicals was suggested.
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