TABLE 2 (continued)
1
2
4e
2.61 (3Н, s, СН3); 3.09 (2Н, m, 3J = 7, СН2); 3.64 (2Н, m, 3J = 7, СН2); 6.53 (1H, dd,
3J = 5, 4J = 1.5, Ar); 7.07 (2H, m, Ar); 7.60 (1H, d, 4J = 1.5, Ar); 7.71 (1H, dd, 3J = 7,
4J = 1.5, Ar); 7.89 (1H, d, 3J = 8, Ar); 8.33 (1H, dd, 3J = 5, 4J = 1.5, Ar); 8.87 (1H, s, =CH)
4f
2.61 (3Н, s, СН3); 3.07 (2Н, t, 3J = 7, СН2); 3.58 (2Н, t, 3J = 7, СН2);
7.11-7.93 (6H, m, Ar); 8.33 (1H, dd, 3J = 5, 4J = 1.5, Ar); 9.08 (1H, s, =CH–)
4g
4h
4i
2.65 (3Н, s, СН3); 3.09 (2Н, t, 3J = 7, СН2); 3.64 (2Н, t, 3J = 7, СН2);
7.13-7.86 (10H, m, Ar); 8.38 (1H, dd, 3J = 5, 4J = 1, Ar); 8.71 (1H, d, 3J = 8, =CH–)
2.61 (3Н, s, СН3); 3.02 (4Н, s, 2СН2); 7.36 (5H, m, Ar); 7.51 (2H, m, 3J = 8, Ar);
7.82 (2H, m, 3J = 8, Ar); 8.89 (1H, s, =CH–)
2.64 (3Н, s, СН3); 3.09 (4Н, s, 2СН2); 7.11-7.47 (7H, m, Ar); 7.91 (2H, m, Ar);
8.93 (1H, s, =CH–)
4j
2.62 (3Н, s, СН3); 3.02 (4Н, s, 2СН2); 3.06 (6Н, s, N(СН3)2); 6.62 (2H, m, 3J = 8, Ar);
7.38 (5H, m, Ar); 7.78 (2H, m, 3J = 8, Ar); 8.71 (1Н, s, =CH–)
4k
4l
2.62 (3Н, s, СН3); 3.02 (4Н, s, 2СН2); 3.82 (3Н, s, СН3); 6.89 (2H, m, 3J = 8, Ar);
7.38 (5H, m, Ar); 7.89 (2H, m, 3J = 8, Ar); 8.78 (1Н, s, =CH–)
2.62 (3Н, s, СН3); 3.04 (4Н, s, 2СН2); 3.89 (3Н, s, OСН3); 3.94 (3Н, s, OСН3);
6.86 (1H, d, 3J = 8, Ar); 7.41 (6H, m, Ar); 7.62 (1H, d, 4J = 2, Ar); 8.81 (1Н, s, =CH–)
4m
4n
4о
4p
2.58 (3Н, s, СН3); 3.01 (4Н, s, 2СН2); 5.96 (2Н, s, СН2); 6.82 (2H, m, 3J = 8, Ar);
7.36-7.51 (6H, m, Ar); 8.78 (1Н, s, =CH–)
2.62 (3Н, s, СН3); 3.09 (4Н, s, 2СН2); 7.38 (6Н, m, Ar); 8.29 (1H, d. t, 3J = 8, 4J = 1.5,
Ar); 8.69 (1H, dd, 3J = 5, 4J = 1.5, Ar); 9.01 (1H, d, 4J = 1.5, Ar); 9.04 (1Н, s, =CH–)
2.62 (3Н, s, СН3); 3.13 (4Н, s, 2СН2); 7.42 (5Н, m, Ar); 7.81 (2H, m, 3J = 5, Ar);
8.69 (2H, m, 3J = 5, Ar); 9.06 (1H, s, =CH–)
2.58 (3Н, s, СН3); 3.04 (4Н, s, 2СН2); 6.56 (1Н, dd, 3J = 4, 4J = 2, Ar); 7.07 (1H, d,
3J = 4, Ar); 7.12-7.47 (5H, m, Ar); 7.61 (1H, d, 4J = 2, Ar); 8.91 (1H, s, =CH–)
4q
4r
2.58 (3Н, s, СН3); 3.02 (4Н, s, 2СН2); 7.07-7.58 (8H, m, Ar); 9.07 (1H, s, =CH–)
2.42 (3Н, s, СН3); 3.04 (4Н, s, 2СН2); 7.16-7.53 (12H, m, Ar, 2=CH–);
8.71 (1H, d, 3J = 9, =CH–)
5а
5b
5с
6а
2.51 (3Н, s, СН3); 2.62 (4Н, s, 2СН2); 2.63-3.02 (4Н, m, 2СН2); 3.04 (3Н, s, СН3);
6.91-7.49 (8H, m, Ar); 9.16 (1H, s, =CH–)
2.49 (3Н, s, СН3); 2.58 (3Н, s, СН3); 2.96 (4Н, s, 2СН2); 2.98-3.38 (4Н, m, 2СН2);
7.13-7.91 (8H, m, Ar); 8.36 (1H, dd, 3J = 5, 4J = 1.5, Ar); 9.16 (1Н, s,=CH–)
2.53 (3Н, s, СН3); 2.62 (3Н, s, СН3); 3.01-3.71 (8Н, m, 4СН2); 7.13 (3H, m, Ar);
7.82 (4H, m, Ar); 8.36 (2H, m, Ar); 9.16 (1H, s, =CH–)
2.61 (3Н, s, СН3); 3.04 (2Н, t, 3J = 7, CH2); 3.64 (2Н, t, 3J = 7, СН2); 7.11 (1H, m, Ar);
7.82 (6H, m, Ar); 8.35 (1H, m, Ar); 8.42 (1Н, d, 3J = 12, =CH–);
11.36 (1H, d, 3J = 12, NH)
6b
7
2.63 (3Н, s, СН3); 3.08 (4Н, s, 2CH2); 7.43-7.78 (9H, m, Ar); 8.52 (1H, d, 3J = 12, =CH–);
11.39 (1H, d, 3J = 12, NH)
1.02 (6Н, s, 2СН3); 2.36 (2Н, s, СН2); 2.38 (2Н, s, СН2); 2.51 (3Н, s, СН3);
3.04 (2Н, t, 3J = 7, CH2); 3.62 (2Н, t, 3J = 7, СН2);
7.04 (1Н, dd. d, 2J = 5, 3J = 7, 4J = 1.5, Ar); 7.69 (1Н, d. t, 3J = 7, 4J = 1.5, Ar);
7.89 (1Н, dd, 3J = 7, 4J = 1.5, Ar); 8.31 (1Н, dd, 3J = 5, 4J = 1.5, Ar);
8.67 (1H, d, 3J = 13, =СH–); 12.16 (1H, d, 3J = 13, NH)
_______
* The 1H NMR spectra of 4e, 4i, 4l, 4p, and 4q were taken in DMSO-d6, the
spectra of the other compounds were taken in CDCl3.
EXPERIMENTAL
The 1H NMR spectra were taken on a Bruker WH-90/DS at 90 MHz using TMS as the internal standard.
The IR spectra were taken on a Specord IR-75 spectrometer for suspensions in vaseline oil at 1800-1500 cm-1
and in hexachlorobutadiene at 3600-2000 cm-1.
The aldehyde samples used were supplied by Acros. The characteristics of 4-7 are given in Tables 1
and 2.
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