Thermolysis of ethyl(methyl)dioxirane
Russ.Chem.Bull., Int.Ed., Vol. 55, No. 10, October, 2006
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Thus, the experimental results indicate a considerable
fraction of radical processes in the system under study.
Temperatures below 30 °C are most optimal when using
EMD as the oxidant, and the use of inert solvents conꢀ
taining no easily oxidizable C—H bonds is reasonable to
avoid undesirable side reactions.
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The isomerization of EMD in butanone affords mainly
ethyl acetate, which agrees with the results of quantum
chemical B3LYP calculations.
In deoxygenated solutions of butanone, the chainꢀ
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This work was financially supported by the Russian
Science Support Foundation and the Division of Chemꢀ
istry and Materials Science of the Russian Academy of
Sciences (Program of Fundamental Research "Theoretiꢀ
cal and Experimental Investigation of the Chemical Bond
Nature and Mechanism of Most Important Chemical Reꢀ
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Received May 26, 2005;
in revised form June 21, 2006