Journal of Organic Chemistry p. 3170 - 3173 (1984)
Update date:2022-08-05
Topics:
Bhatt, M. Vivekananda
Ravindranathan, M.
Somayaji, Viswanatha
Rao, G. Venkoba
The rates of alkaline hydrolysis of methyl β-benzoylpropionate (I), methyl γ-benzoylbutyrate (II) and methyl δ-benzoylvalerate (III) decrease in the order I>II>III.Keto participation is the predominant pathway in the case of γ-keto esters.Evidence has also been obtained for keto participation in the case of δ-keto esters, whereas no such evidence is available in the case of ε-keto esters studied.
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