Inorganic Chemistry p. 3132 - 3138 (1979)
Update date:2022-09-26
Topics:
Brzezinska
Cullen
A number of soluble (chlorosilyl)phosphine complexes of rhodium(I) which are capable of being polymerized into poly(siloxyphosphine)-rhodium(I) species have been synthesized and characterized. They are L2′Rh(CO)Cl, L′3RhCl, L″3RhCl, and L′4Rh2Cl2 (L′ = Cl3Si(CH2)2P(C6H5) 2, L″ = Cl3Si(CH2)8P(C6H5) 2). Soluble siloxyphosphine-rhodium(I) complexes LRh(NBD)Cl, L2Rh(CO)Cl, L3RhCl, and L4Rh2Cl2 (NBD = norbornadiene, L = [(CH3)3SiO]2(CH3)Si(CH 2)2P(C6H5)2) have also been synthesized and characterized and their reactions with gaseous H2, CO, and HCl as well as their catalytic behavior in hydrogenation reactions have been studied. These complexes were prepared to serve as study models for their polymeric counterparts.
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(2021)
