Tetrahedron Asymmetry p. 2355 - 2359 (1997)
Update date:2022-08-03
Topics:
Fadnavis
Kumara Vadivel
Bhalerao
Baker's yeast mediated reduction of α-substituted-β-ketoesters lead to reduction of the carbonyl group with high enantiospecificity and diastereoselectivity at low pH (4.0-5.0, e.e. >99%, d.e. >90%) but cleavage of the C-C bond is observed at higher pH >8.0). Similar carbon-carbon bond cleavages are observed in the reactions of α-acetamido-β-ketoesters and acetamidocinnamic acid.
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