The Use of Grignard Reagents in the Synthesis of Carbohydrates. III. The One-way Anomerization of Methyl Glycofuranosides and the Opening of Their Furanose Rings

DOI: 10.1246/bcsj.54.1492

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1492 - 1504 (1981)

Update date:2022-08-04

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Authors:

Kawana, Masajiro

Kuzuhara, Hiroyoshi

Emoto, Sakae

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Article abstract of DOI:10.1246/bcsj.54.1492

The anomerization of methyl glycofuranoside derivatives with methylmagnesium iodide or t-butylmagnesium bromide occurred in a one-way manner.For example, methyl 5-O-benzyl-β-D-ribofuranoside (3β) was converted into the corresponding α-anomer (3α) in a 95p

Full text of DOI:10.1246/bcsj.54.1492

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Article Doi

The Use of Grignard Reagents in the Synthesis of Carbohydrates. III. The One-way Anomerization of Methyl Glycofuranosides and the Opening of Their Furanose Rings

DOI: 10.1246/bcsj.54.1492

Source and publish data:

Authors:

Article abstract of DOI:10.1246/bcsj.54.1492

Full text of DOI:10.1246/bcsj.54.1492

Products guided by the article

R&D Labs maybe for 58109-23-2

Relevant to this article

Stereoselective preparation of N-[(R,R)-(E)-1-(3,4-dichlorobenzyl)-3-(2-oxoazepan-3-yl)carbamoyl]allyl- N-methyl-3,5-bis(trifluoromethyl)benzamide, a potent and orally active dual neurokinin NK1/NK2 receptor antagonist

Synthesis of poly (3,4,5-trihydroxybenzoate ester) dendrimers and their chemiluminescence

Reactions of some 2- and 4-O-triflylglycopyranosides with MeLi, t-BuOK, and pyridine

An Improvment of the Anderson Test by the Use of High Performance Liquid Chromatography

Stereoselective preparation of N-[(R,R)-(E)-1-(3,4-dichlorobenzyl)-3-(2-oxoazepan-3-yl)carbamoyl]allyl- N-methyl-3,5-bis(trifluoromethyl)benzamide, a potent and orally active dual neurokinin NK₁/NK₂ receptor antagonist