Tetrahedron Letters p. 945 - 948 (2003)
Update date:2022-09-26
Topics:
Díaz, Marta C.
Illescas, Beatriz
Martín, Nazario
A novel p-quinonoid π-extended tetrathiafulvalene (exTTF) endowed with four hydroxy groups with different reactivity (phenol and alcohol) has been synthesized as a supramolecular redox building block. The redox properties, studied by cyclic voltammetry, reveal a strong donor ability and, despite the different substitution pattern on the 1,3-dithiole rings, only one oxidation wave involving two electrons to form the dication species.
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