Russian Chemical Bulletin p. 2220 - 2225 (1998)
Update date:2022-07-29
Topics:
Zyk
Beloglazkina
Tyurin
Grishin
Bromochlorination of norbornene whose chemo- and regio-selectivity is determined by the type of the halogenating reagent used was studied. Three isomeric bromochloronorbornanes (2-endo-bromo-3-exo-chloro-, 2-exo-bromo-3-endo-chloro-, and 2-exo-bromo-7-syn-chlorobicyclo[2.2.1.]heptanes), 2-exo-7-syn- and 2-exo-7-anti-dibromo- and -dichloro-norbornanes, and 2-bromonortricyclane were isolated and characterized by 1H and 13C NMR spectra. The spectral and structural characteristics of the resulting compounds are discussed.
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