Molecules 2002, 7
410
Compound 2: IR νmax. KBr (cm-1): 3238, 3211, 3134, 3067, 2993, 2940, 1601, 1447, 1180, 1054, 1035,
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860, 748, 551, 435, 315; H-NMR (200 MHz; DMSO-d6) δ: 1.96 (m, 2H, CH2); 2.37 (m, 2H,
CH2NH2); 2.79 (sl ,2H, CH2NH); 4.09; 4.84 (2m, 2H, H7, H7’); 5.78; 6.63 (2m, 3H, NH2, NH); 7.42;
7.44 (2d, 2H, H3, H6); 7.51; 8.22 (2t, 2H, H4, H5); 13C-NMR (50 MHz, CDCl3) δ: 22.99; 41.81;
51.20; 54.21 (CH2); 127.28; 129.57; 131.03; 132.16; 133.86; 135.19 (Ph); 195Pt-NMR (86 MHz,
DMSO-d6) δ: - 2250; Anal. Calcd. for C10H15Cl3N2Pt: C: 25.85; H: 3.25; N: 6.03; found: C: 26.26; H:
3.48; N: 5.71.
Compound 3: IR νmax. KBr (cm-1): 3244, 3207, 3135, 3030, 2934, 2879, 1596, 1575, 1492, 1180, 1092,
1013, 848, 815, 527, 493, 320; 1H-NMR (400 MHz; DMSO-d6) δ: 1.75 (m, 2H, CH2); 2.49; 2.70 (2m,
4H, CH2NH2, CH2NH); 3.92; 4.33 (2dd, 2H, H7, H7’, J7-7’= 12 Hz, J7-NH= 4 Hz, J7’-NH= 4 Hz); 5.20;
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6.16 (2sl, 3H, NH2, NH); 7.44; 7.52 (2d, 4H, Ph); C-NMR (100 MHz, DMSO-d6) δ: 23.10; 42.39;
47.70; 55.07 (CH2); 128.13; 128.42; 131.89; 132.03 (Ph); 195Pt-NMR (86 MHz, DMSO-d6) δ: - 2248;
Anal. Calcd. for C10H15N2Cl3Pt: C: 25.85; H: 3.25; N: 6.03; found: C: 26.37; H: 3.27; N: 5.91.
Compound 4: IR νmax. KBr (cm-1): 3258, 3228, 3111, 2951, 2935, 1609, 1516, 1459, 1350, 1190, 1109,
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848, 706, 530, 327; H-NMR (400 MHz; DMSO- d6) δ: 1.88 (m, 2H, CH2); 2.75 (sl, 2H, CH2NH2);
2.85 (t, 2H, CH2NH); 4.00; 4.46 (2m, 2H, H7, H7’); 5.17; 6.37 (2sl, 3H, NH2, NH); 8.04; 8.28 (2d, 4H,
Ph); 13C-NMR (100 MHz, DMSO-d6) δ: 23.17; 42.53; 49.05; 55.22 (CH2); 123.10; 131.69; 132.55;
147.03 (Ph); 195Pt-NMR (86 MHz, DMSO-d6) δ: - 2236; Anal. Calcd. for C10H15N3Cl2O2Pt: C: 25.27;
H: 3.18; N: 8.84; found: C: 25.05; H: 3.38; N: 8.56.
Compound 5: IR ν KBr (cm-1): 3245, 3216, 3168, 3144, 3004, 2938, 1611, 1513, 1460, 1253, 1177,
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1030, 817, 554, 329; H-NMR (400 MHz; DMSO-d6) δ: 1.49 (m, 2H, CH2); 2.40; 2.49 (2m, 4H,
CH2NH2, CH2NH); 3.72 (s, 3H, OCH3); 3.92; 4.33 (2dd, 2H, H7’, H7’); 5.12; 5.85 (2sl, 3H, NH2,
NH); 6.88; 7.32 (2d, 4H, Ph); 13C-NMR (100 MHz, CDCl3) δ: 23.06; 42.43; 47.05; 55.14 (CH2); 55.22
(OCH3);113.58; 131.07; 131.87; 132.45; 158.86 (Ph); 195Pt-NMR (86 MHz, DMSO-d6) δ: - 2256;
Anal. Calcd. for C11H18N2Cl2OPt: C: 28.71; H: 3.94; N: 6.09; found: C: 28.77; H: 4.03; N: 5.93.
Compound 6: IR ν KBr (cm-1): 3159, 3012, 2980, 1576, 1498, 1453, 1433, 1211, 994, 748, 697, 523,
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325, 315; H-NMR (400 MHz; DMSO-d6) δ: 2.08 (m, 2H, CH2); 3.03 (sl, 4H, CH2NH); 4.14 (sl, 4H,
CH2Ph); 7.44; 7.56 (2d, 10H, Ph); Anal. Calcd. for C17H22N2Cl2Pt·4H2O: C: 34.46; H: 5.10; N: 4.72;
found: C: 34.60; H: 4.67; N: 4.84.
Compound 7: IR ν KBr (cm-1): 3229, 3208, 3127, 3049, 2953, 1596, 1529, 1450, 1352, 1140, 1048,
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813, 736, 702, 472, 324; H-NMR (400 MHz; DMSO-d6) δ: 1.71 (m, 2H, CH2); 2.64; 2.66 (2t, 4H,
CH2NH2, CH2NH); 3.94; 4.44 (2sl, 2H, H7, H7’); 5.15; 6.42 (2sl, 3H, NH2, NH); 7.68 (sl ,1H, H5);
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8.08; 8.22 (2d, 2H, H4, H6, J4-5= J5-6= 6.8 Hz); 8.51 (s, 1H, H2); C-NMR (100 MHz, DMSO-d6) δ:
23.10; 42.52; 49.19; 58.13 (CH2); 122.74; 125.24; 125.26; 129.46; 137.25; 147.38 (Ph); 195Pt-NMR