Russian Chemical Bulletin p. 1360 - 1364 (2000)
Update date:2022-07-29
Topics:
Zakharova
Valeeva
Shagidullina
Kudryavtseva
The catalytic effect of the sodium dodecyl sulfate - hexanol - water ternary reverse micellar system in the alkaline hydrolysis of O-alkyl O′-aryl chloromethylphosphonates as a function of the substrate structure was studied. The micellar effect is mainly determined by a change in the electronic properties of the substituents, while the hydrophobicity plays a secondary role. The kinetic data were examined in the framework of the pseudo-phase model of micellar catalysis. The rate constants of the reaction in the surface layer and the partition constants of the reactants were calculated.
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