Tetrahedron p. 2771 - 2784 (1994)
Update date:2022-08-04
Topics:
Natori, Takenori
Morita, Masahiro
Akimoto, Kohji
Koezuka, Yasuhiko
New glycosphingolipids, named agelasphins (1-8), have been isolated by antitumor and immunostimulatory bioassay-guided purification from an extract of a marine sponge, Agelas mauritianus. Strongly active agents in agelasphins had characteristic α-galactosylceramide structures, the isolation of which from natural products has not previously been reported. The absolute configurations of agelasphins were elucidated by the total synthesis.
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