An Alternative Convenient Biaryl Synthesis
FULL PAPERS
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SiX2F(–) was responsible to facilitate the transmetalation
of the phenyl group to the oxidative adduct ArPdX. The
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transformed to a hexacoordinate silicate species rather
than the transmetalation as evidenced previously by
our group in the cross-couplings using aryltrifluorosi-
lanes. However, this is our presumption and we do not
have sufficient data to prove it.
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Adv. Synth. Catal. 2004, 346, 1715–1727
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