10.1002/ejoc.202000599
European Journal of Organic Chemistry
FULL PAPER
1H, Hd’), 7.92 (dd, 3JH,H = 8.0 Hz, 4JH,H = 1.7 Hz, 1H, Hb’), 7.88 (s, 1H, Hd),
7.84 (d, 3JH,H = 8.4 Hz, 2H, Hb’’), 7.61 (d, 3JH,H = 8.4 Hz, 2H, Ha’’), 7.60 (d,
Dalton Trans. 2013, 42, 8575-8584; d) W. Yi, H. Ma, Dalton Trans. 2014,
43, 5200-5210.
3
4
4JH,H = 1.7 Hz, 1H, Ha’), 7.55 (d, JH,H = 8.0 Hz, 1H, Hc’), 7.43 (d, JH,H
=
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4JH,H = 1.4 Hz, 1H, Ha), 7.14 (dd, JH,H = 9.1 Hz, JH,H = 2.8 Hz, 1H, Hf),
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3
4
7.12 (d, JH,H = 1.4 Hz, 1H, Hb), 7.00 (d, JH,H = 2.8 Hz, 1H, Hh), 6.72 (d,
4
4
3JH,H = 9.1 Hz, 1H, He’), 6.47 (d, JH,H = 9.1 Hz, 1H, He), 3.87 (s, 3H,
3
CO2CH’3), 3.80 (s, 3H, CO2CH’’3), 2.34 ppm (s, 3H, CH3); 13C NMR (151
MHz, DMSO-d6): δ 174.0 (C7), 170.3 (C9’), 170.1 (C9), 167.7 (C7’), 165.9
(C’’O2CH3), 165.6 (C’O2CH3), 147.7 (C2’), 143.6 (C1’’), 143.5 (C2), 137.6
(C1’), 137.3 (C13’), 137.1 (C11), 136.9 (C11’ + C13), 136.2 (C5), 135.3 (C3),
132.2 (C1), 131.9 (C4), 131.4 (C6), 130.8 (C6’), 130.3 (C2’’), 130.0 (C4’),
129.0 (C3’’), 127.8 (C4’’), 126.9 (C5’), 125.4 (C10’), 124.7 (C10), 123.3 (C3’),
120.7 (C8), 119.8 (C8’), 103.0 (C12’), 102.5 (C12), 52.4 (CO2C’H3), 52.1
(CO2C’’H3), 20.2 ppm (CH3); LRMS (ESI): m/z (%): 838.934 (39) [M+Na]+;
HRMS (ESI): m/z calcd for C37H26Br2N2O6Zn+Na: 838.9341 [M+Na]+;
found: 838.9340; elemental analysis calcd (%) for C37H26Br2N2O6Zn: C
54.21, H 3.20, N 3.42; found: C 53.95, H 3.18, N 3.39.
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The Research Council of Norway is kindly acknowledged for
funding through project no. 228157 (stipend to K.T.H). This work
was also partly supported by the Research Council of Norway
through the Norwegian NMR Package in 1994 and partly
supported by the Research Council of Norway through the
Norwegian NMR Platform, NNP (226244/F50). Additional support
by the Department of Chemistry and the Faculty of Mathematics
and Natural Sciences at University of Oslo is also acknowledged.
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