Chemistry of Heterocyclic Compounds p. 1324 - 1327 (1988)
Update date:2022-08-04
Topics:
Volynskii, N. P.
Perepelitchenko, L. I.
We have developed a three-stage scheme for the preparative synthesis of 2-substituted tetrahydrofurans from allyl halides and aldehydes to give the first stage - a Grignard reaction - mixed alkoxides, which on treatment with acetic anhydride are converted to 4-acetoxy-1-alkenes.Addition of hydrogen bromide to the latter contrary to Markownikoff's rule gives 4-acetoxy-1-bromoalkanes, which as a result of hydrolysis form 2-R-tetrahydrofurans.
View MoreContact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
CGeneTech (Suzhou, China) Co., Ltd.
Contact:+86-512-62956962
Address:Room 101,Bld C11,218 Xinghu Rd.,Suzhou industrial Park
Qingzhou Baibang import and export co.,Ltd
Contact:+86-536-3265899
Address:No.338, Tuoshan Road
ClickChem Technology Co., Limited
Contact:+86-0310-6519966/0531-52893837
Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Jinan Jianfeng Chemical Co., Ltd
Contact:0086-531-88110457
Address:sales01(-a-t-)pharmachemm{dot}c+o+m
Doi:10.1246/bcsj.51.535
(1978)Doi:10.1002/anie.200503299
(2006)Doi:10.1002/jlac.198319831010
(1983)Doi:10.1016/j.tetlet.2005.12.127
(2006)Doi:10.1007/BF00758838
(1984)Doi:10.1002/anie.202108499
(2021)