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Green Chemistry
Page 4 of 6
COMMUNICATION
Journal Name
Chem., 2015, 17, 5189-5195.
extraction and thionation process using biomass derived crude
LA solution as substrate which provided a quite satisfying yield
DOI: 10.1039/C6GC00566G
20. J. Tukacs, D. Király, A. Strádi, G. Novodarszki, Z. Eke, G. Dibó, T.
Kégl and L. Mika, Green Chem., 2012, 14, 2057-2065.
21. J. Tukacs, M. Novák, G. Dibó and L. Mika, Catal. Sci. Technol.,
2014, 4, 2908-2912.
22. J. Tukacs, R. Jones, F. Darvas, G. Dibó, G. Lezsák and L. Mika, RSC
Adv., 2013, 3, 16283-16287.
of 5. Moreover, LR residue can be removed by simply washing
by NaHCO3 solution, which facilitates further purification and
application of the desired products. Notably, the aromatic
structure and thiol group of
5 ensures its versatility for
downstream conversion into various peculiar building blocks for
functional materials, pharmaceutical intermediates and solvent
applications, which include that a) thiophene, sulfoxide and
sulphone compounds by the hydrogenation/oxidization of
thiophene ring or thiol group; b) thiophene aldehyde,
thiophene carboxylic acid and halothiophene by substitution
reactions on the aromatic thiophene ring; c) thienothiophene
23. V. Fábos, L. Mika and I. Horváth, Organometallics, 2014, 33,
181-187.
24. Y. Wang, F. Vogelgsang and Y. Román-Leshkov, ChemCatChem,
2015, 7, 916-920.
25. L. Wu, S. Dutta and M. Mascal, ChemSusChem, 2015, 8, 1167-
1169.
26. S. Dutta, L. Wu and M. Mascal, Green Chem., 2015, 17, 2335-
2338.
27. A. Touchy, S. Hakim Siddiki, K. Kon and K. Shimizu, ACS Catal.,
2014, 4, 3045-3050.
28. J. Vidal, M. S. Climent, P. Concepcion, A. Corma, S. Iborra and M.
Sabater, ACS Catal., 2015, 5, 5812-5821.
29. Y. Huang, J. Dai, X. Deng, Y. Qu, Q. Guo and Y. Fu,
ChemSusChem, 2011, 4, 1578-1581.
30. Y. Wei, C. Wang, X. Jiang, D. Xue, Z. Liu and J. Xiao, Green Chem.,
2014, 16, 1093-1096.
compounds, which is proposed to be synthesized from
alkylating the thiol group followed by annulation.
5 by
We thank for the financial support by the National Natural
Science Foundation of China (21506177), the Natural Science
Foundation of Fujian Province of China (2015J05034), the Key
Program for Cooperation between Universities and Enterprises
in Fujian Province (2013N5011), and the Fujian Provincial
Development and Reform Commission (2015489), China.
31. Y. Ogiwara, T. Uchiyama and N. Sakai, Angew. Chem. Int. Ed.
Engl., 2016, 55, 1864-1867.
32. K. Omari, L. Dodot and F. Kerton, ChemSusChem, 2012, 5, 1767-
1772.
33. M. Drover, K. Omari, J. Murphy and F. Kerton, RSC Adv., 2012, 2,
4642-4644.
34. J. Yamaguchi, A. D. Yamaguchi and K. Itami, Angew. Chem. Int.
Ed. Engl., 2012, 51, 8960-9009.
35. S. Zhao, J. Yuan, Y. Li and B. Shi, Chem. Commun. (Camb), 2015,
51, 12823-12826.
36. J. Rentner and R. Breinbauer, Chem. Commun. (Camb), 2012, 48,
10343-10345.
37. N. Kojima, T. Fushimi, T. Tatsukawa, T. Tanaka, M. Okamura, A.
Akatsuka, T. Yamori, S. Dan, H. Iwasaki and M. Yamashita, Eur. J.
Med. Chem., 2014, 86, 684-689.
38. Y. Cheng, S. Yang and C. Hsu, Chem. Rev., 2009, 109, 5868-5923.
39. C. Wang, H. Dong, W. Hu, Y. Liu and D. Zhu, Chem. Rev., 2012,
112, 2208-2267.
References
1. D. M. Alonso, J. Q. Bond and J. A. Dumesic, Green Chem., 2010,
12, 1493-1513.
2. M. Mascal, S. Dutta and I. Gandarias, Angew. Chem. Int. Ed. Engl.,
2014, 53, 1854-1857.
3. M. Mascal and E. B. Nikitin, Angew. Chem. Int. Ed. Engl., 2008, 47,
7924-7926.
4. B. Girisuta, L. Janssen and H. Heeres, Chem. Eng. Res. Des., 2006,
84, 339-349.
5. J. Bozell, L. Moens, D. Elliott, Y. Wang, G. Neuenscwander, S.
Fitzpatrick, R. Bilski and J. Jarnefeld, Resour. Conserv. Recycl.,
200, 28, 227-239.
6. P. Gallezot, Chem. Soc. Rev., 2012, 41, 1538-1558.
7. G. Akien, L. Qi and I. Horvath, Chem. Commun. (Camb), 2012, 48,
5850-5852.
8. Á. Szabolcs, M. Molnár, G. Dibó and L. Mika, Green Chem., 2013,
15, 439-445.
40. T. Ozturk, E. Ertas and O. Mert, Chem. Rev., 2007, 107, 5210-
5278.
41. T. Ozturk, E. Ertas and O. Mert, Chem. Rev., 2010, 110, 3419-
3478.
9. I. Horváth, H. Mehdi, V. Fábos, L. Boda and L. Mika, Green Chem.,
2008, 10, 238-242.
10. H. Mehdi, V. Fábos, R. Tuba, A. Bodor, L. Mika and I. Horváth,
Top. Catal., 2008, 48, 49-54.
42. T. R. Carlson, G. A. Tompsett, W. C. Conner and G. W. Huber,
11. E. Ismalaj, G. Strappaveccia, E. Ballerini, F. Elisei, O. Piermatti, D.
Gelman and L. Vaccaro, ACS Sustain. Chem. Eng., 2014, 2, 2461-
2464.
12. Z. Yan, L. Lin and S. Liu, Energy Fuels, 2009, 23, 3853-3858.
13. X. L. Du, L. He, S. Zhao, Y. M. Liu, Y. Cao, H. Y. He and K. N. Fan,
Angew. Chem. Int. Ed. Engl., 2011, 50, 7815-7819.
14. M. Chia and J. A. Dumesic, Chem. Commun. (Camb), 2011, 47,
12233-12235.
Top. Catal., 2009, 52, 241-252.
43. A. Zheng, Z. Zhao, S. Chang, Z. Huang, K. Zhao, H. Wu, X. Wang,
F. He and H. Li, Green Chem., 2014, 16, 2580.
45. S. Thiyagarajan, H. C. Genuino, J. C. van der Waal, E. de Jong, B.
M. Weckhuysen, J. van Haveren, P. C. Bruijnincx and D. S. van
Es, Angew. Chem. Int. Ed. Engl., 2016, 55, 1368-1371.
46. G. Zotti and B. Vercelli, Chem. Mater., 2008, 20, 397-412.
47. J. Hutton, A. Jones, S. H. Lee, D. Martin, B. Meyrick, I. Patel, R.
Peardon and L. Powell, Org. Process Res. Dev., 1997, 1, 61-67.
48. J. Eiserich, J. Wong and T. Shibamoto, J. Agric. Food Chem.,
1995, 43, 647-650.
15. X. Tang, H. Chen, L. Hu, W. Hao, Y. Sun, X. Zeng, L. Lin and S. Liu,
Appl. Catal., B, 2014, 147, 827-834.
16. X. Tang, X. Zeng, Z. Li, L. Hu, Y. Sun, S. Liu, T. Lei and L. Lin,
Renewable Sustainable Energy Rev., 2014, 40, 608-620.
17. Z. Li, X. Tang, Y. Jiang, Y. Wang, M. Zuo, W. Chen, X. Zeng, Y. Sun
and L. Lin, Chem. Commun. (Camb), 2015, 51, 16320-16323.
18. X. Tang, Z. Li, X. Zeng, Y. Jiang, S. Liu, T. Lei, Y. Sun and L. Lin,
ChemSusChem, 2015, 8, 1601-1607.
49. S. Sklenak, Y. Apeloig and Z. Rappoport, J. Chem. Soc., Perkin
Trans. 2, 2000, 2269-2279.
4 | J. Name., 2012, 00, 1-3
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