Journal of Fluorine Chemistry p. 257 - 267 (1992)
Update date:2022-07-29
Topics:
Clark, James H.
McClinton, Martin A.
Blade, Robert J.
1,1,1-Trifluoro-2-arylethanes can be prepared by the trifluoromethyldehydroxylation of benzyl alcohols using the copper-dibromodifluoromethane-amide reaction system, although the yields are low.The mechanism of the reaction may involve chelation of the substrate to copper so that α-substituted benzyl alcohols and other alcohols are unreactive.
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