Inorganic Chemistry
Article
from the Schlenk tube and passed through a short column of silica gel
with DCM as the eluent to give the sample for GC/MS analysis.
Another 0.5 mL of the reaction mixture was directly added into a
NMR tube for NMR analysis, and the yields of the products were
determined by integration in the 19F NMR spectrum versus internal
PhCF3. For C−N bond formation, 0.2 mmol of TMS-NEt2 and 0.2
mmol of CsF were used and the reaction temperature was 100 °C
(except for that of PFNB). For C−S bond formation, 0.12 mmol of
TMS-SEt was used and the typical temperature was 25 °C.
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ASSOCIATED CONTENT
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The Supporting Information is available free of charge on the
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Detailed experimental procedures and characterization of
new compounds, crystallographic data, and coordinates
of the DFT-optimized intermediates and transition states
AUTHOR INFORMATION
Corresponding Authors
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Klaring, P. Organometallics 2012, 31, 1417.
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Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
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This project was supported by the National Key Basic Research
Support Foundation of China (Grants 2010CB912302 and
2015CB856301) and National Scientific Foundation of China
(Grants 20971007, 21571007, 21271013, 21321001, and
21101169).
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