Journal of Organic Chemistry p. 5163 - 5166 (1981)
Update date:2022-07-30
Topics: Lactones Thiol Ring-Opening Reaction Hard Acid Soft Nucleophile Aluminum Halide ω-Alkylthio or ω-Arylthio Carboxylic Acids
Node, Manabu
Nishide, Kiyoharu
Ochiai, Masahito
Fuji, Kaoru
Fujita, Eiichi
Lactones were converted into ω-alkylthio carboxylic acids in high yields through ω-carbon-oxygen bond cleavage when they were treated with aluminun halide and alkanethiol.The aluminum halide and arenethiol system has also been found to be useful for the preparation of the synthetically valuable ω-arylthio carboxylic acids from lactones.
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