Journal of Organic Chemistry p. 1718 - 1722 (1992)
Update date:2022-08-02
Topics:
Cardellicchio, Cosimo
Fiandanese, Vito
Naso, Francesco
(E)- and (Z)-halovinyl aryl sulfoxides 1-4 were subjected to reactions with organocopper, organomagnesium, or organolithium reagents.The organometallic reagents gave different products: diorganocuprates led to formation of carbon-carbon bond, with production of alkenyl sulfoxides 5-10, whereas formation of carbon-sulfur bond and production of diaryl or aryl alkyl sulfoxides 11-13 were observed in the reaction with the other organometallics.Possible mechanisms for the two observed processes are briefly discussed.
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