Bulletin of the Chemical Society of Japan p. 224 - 238 (1982)
Update date:2022-08-05
Topics: Aldehydes Organic synthesis Carbonyl derivatives Silyl Phosphites α-(Trimethylsilyloxy)-alkylphosphonates
Sekine, Mitsuo
Nakajima, Masashi
Kume, Akiko
Hashizume, Akio
Hata, Tsujiaki
Carbonyl addition compounds of diethyl trimethylsilyl phosphite (DTMSP) with aldehydes were converted, by treatment with lithium diisopropylamide (LDA) followed by the successive alkylation and alkaline hydrolysis, to carbonyl derivatives involving aldehydes, unsymmetrical ketones, β,γ-unsaturated ketones, and carboxylic acids. β-Substituted carboxylic esters and γ-substituted lactones were prepared by use of the carbonyl addition compounds of DTMSP with α,β-unsaturated aldehydes.
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