Journal of Organic Chemistry p. 624 - 632 (2017)
Update date:2022-09-26
Topics:
Qiu, Di
Wang, Shuai
Meng, He
Tang, Shengbo
Zhang, Yan
Wang, Jianbo
An efficient stannylation process with N-tosylhydrazones or directly with carbonyl compounds has been developed. A series of functionalized benzyl- and alkyltributylstannanes can be synthesized in moderate to good yields under transition-metal-free conditions. Tandem transformations involving stannylation/Stille cross-coupling reaction have been carried out without purification of the benzyltributylstannane intermediates to afford a series of diarylmethane derivatives.
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