Journal of Organic Chemistry p. 4278 - 4280 (1980)
Update date:2022-08-05
Topics:
Tempesti, E.
Montoneri, E.
Giuffre, L.
Airoldi, G.
Sulfur dioxide has been found to promote a novel liquid-phase oxidation of cyclohexene with molecular oxygen in acetic acid as solvent.Oxidation at the allylic position occurs only if the reaction is base-catalyzed; with added acetoxy ions, e.g., the major product obtained is 2-cyclohexen-1-one together with minor amounts of 1,2-cyclohexanediol diacetate (mainly as the trans isomer), while a competitive autoxidation of sulfur dioxide to sulfur trioxide is observed.The results are discussed on the basis of an anion-radical mechanism involving the formation of sulfur dioxide stabilized peroxide ions.
View MoreChemsky(shanghai)International Co.,Ltd.
Contact:0
Address:0
Suzhou Health Chemicals Co., Ltd.
website:http://www.healthchems.com
Contact:13776257979
Address:No. 338, Jingang Avenue,
Jinan Boss Chemical Industry Co., Ltd.
website:http://www.chemboss.com.cn
Contact:+86-531-58591595
Address:No2.Hualong Road, Jinan, China
website:http://www.hanwayschem.com
Contact:+86-18502787239(whatsapp)
Address:18-1-802, Green Garden, Jianghan District, Wuhan 430023, China
Contact:86-571-85586718
Address:join hands science park,NO.4028 nanhuan road,hanghzou ,zhejiang,china
Doi:10.1016/0008-6215(83)85007-1
(1993)Doi:10.1016/j.tet.2007.03.144
(2007)Doi:10.1039/j19690001378
(1969)Doi:10.1021/ja01562a050
(1957)Doi:10.1021/jo01310a010
(1980)Doi:10.1246/bcsj.60.563
(1987)