Russian Journal of General Chemistry p. 708 - 710 (2005)
Update date:2022-08-02
Topics:
Kochina
Vrazhnov
Sinotova
Ignat'ev
The gas-phase reaction of diethylsilylium ions with hexamethyldisiloxane was studied by the radiochemical procedure. As in reactions with other nucleophiles, the degree of rearrangement of the diethylsilylium ion in the reaction with hexamethyldisiloxane correlates with the condensation energy. In contrast to the reaction of Et2SiT+ with dibutyl ether, in the reaction with hexamethyldisiloxane the labeled substrate is formed, which is due to isomerization of the trimethylsilyl substituent giving rise to a labile hydrogen atom. 2005 Pleiades Publishing, Inc.
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