Journal of Organic Chemistry p. 231 - 234 (1981)
Update date:2022-08-05
Topics:
Clive, Derrick L.J.
Kale, Vilas N.
A variety of β-oxygenated selenides, as exemplified by phenylseleno lactones, ethers, and alcohols are converted into olefins by treatment with Me3SiCl and NaI in MeCN; the reaction is stereospecific and can be extended to iodo and thio species.The conversion of 1,3, and 4 into 2-cyclopentene-1-acetic acid, of 5 into 2-(2-cyclopenten-1-yl)ethanol, and of 9 into (Z)-oct-4-ene illustrates the process.
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