Journal of the Chemical Society. Perkin transactions I p. 1450 - 1457 (1980)
Update date:2022-07-30
Topics: Intermediates Rearrangements Ylide Base catalysed Stevens <1,2> Sigmatropic Rearrangement Stevens <3,2> Sigmatropic Rearrangement Allylic ammonium ylides
Jemison, Robert W.
Laird, Trevor
Ollis, W. David
Sutherland, Ian O.
The base catalysed rearrangements of the quaternary ammonium salts (9) usually gives the <3,2> sigmatropic rearrangement product (10) rather than the Stevens <1,2> rearrangement product (11).An earlier claim has been corrected: the corresponding reaction
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