Journal of Organometallic Chemistry p. 87 - 98 (1982)
Update date:2022-08-05
Topics:
Gustavson, Wayne A.
Epstein, Paul S.
Curtis, M.D.
Redistribution reactions of a variety of hydrogen-substituted siloxanes are catalyzed by various transition metal complexes of iridium and rhodium.The products arise from breaking and remaking of Si-C, Si-H, and Si-O bonds.Siloxanes not possessing a Si-H bond are inert under the conditions studied.The most favored reaction pathway appears to scramble preferentially the groups directly attached to the silicon bearing the hydrogen atom.A new cyclo-iridiadisiloxane,
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