Tetrahedron Letters p. 3595 - 3598 (1993)
Update date:2022-09-26
Topics:
Benati
Montevecchi
Nanni
Spagnolo
Mild reaction of phenyl vinyl sulfides with dioxygen can lead to the eventual formation of rearranged vinyl sulfides and/or carbonyl-containing sulfide products, which are believed to result from decomposition of initially-formed vinyl sulfide radical cations. Supporting evidence is provided by the comparable findings obtained from the one electron oxidation of one vinyl sulfide by cerium (IV) ammonium nitrate.
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(2021)
