Tetrahedron Letters p. 679 - 682 (1981)
Update date:2022-08-06
Topics:
Harrison, John M.
Inch, Thomas D.
Under mild conditions, nucleophiles add across the cyanide moiety of CS epoxide rather than opening the ring.With hydroxide ion in peroxide-free aqueous dioxan isomeric amides are obtained.Hydrolysis in peroxide containing dioxan affords a novel rearrangement involving carbon-carbon bond fission of the dioxan.
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