Tetrahedron Asymmetry p. 2619 - 2625 (1998)
Update date:2022-08-03
Topics:
Lattanzi, Alessandra
Bonadies, Francesco
Schiavo, Annamaria
Scettri, Arrigo
Enantiomerically enriched β-keto sulfoxides are obtainable by an alternative method to the classical reaction of the enantiomerically pure α- sulfinyl anion with esters or by Anderson's synthesis, through Sharpless modified kinetic resolution of racemic β-keto sulfoxides. High e.e.s are achieved by combining asymmetric oxidation and kinetic resolution using furylhydroperoxides as oxidants.
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