Journal of Organometallic Chemistry p. 29 - 42 (1982)
Update date:2022-08-02
Topics:
Erker, Gerhard
Rosenfeldt, Frank
Thermolysis of η2-benzoyl(phenyl)zirconocene yields the η2-benzophenonzirconocene complex 2, isolated as a dimer. 2 exhibits an ambivalent reactivity pattern.The formation of five-membered metallacycles from 2 and olefinic hydrocarbons possibly proceeds analogous to reactions of "normal" metal-olefin ?-complexes.However, both reactions with the electron-deficient olefins dimethylfumarate and -maleate and the behavior towards electrophilic and protic reagents as well as aromatic hydrocarbons might be interpreted in terms of a metallaoxirane-character of 2.
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Doi:10.1021/ja01252a039
(1943)Doi:10.1248/cpb.42.1157
(1994)Doi:10.1021/jo991645o
(2000)Doi:10.1007/BF00958404
(1982)Doi:10.1016/S0022-328X(00)85843-X
(1982)Doi:10.1021/jo00136a006
(1982)
