Organic Letters
Letter
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Scheme 5. Proposed Mechanism
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In summary, an efficient photoinduced oxo-sulfonylation of
ynamides with easily available and inexpensive sulfonic acids has
been developed. A variety of α-sulfonylated amides were
obtained by a tandem electrophilic addition/photoinduced
radical rearrangement process. In addition, this reaction features
good atom economy, mild reaction conditions, broad substrate
scope, and excellent chemoselectivity. Moreover, this reaction
provides an alternative strategy for α-sulfonylated amides which
are important precursors in chemical transformations.
ASSOCIATED CONTENT
* Supporting Information
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S
The Supporting Information is available free of charge on the
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General information, Experimental Section, mechanistic
study, 1H and 13C spectra (PDF)
AUTHOR INFORMATION
Corresponding Authors
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ORCID
Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
■
We gratefully acknowledge the financial support of the
“Thousand Talents Plan” Youth Program, the “Jiangsu
Specially-Appointed Professor Plan”, the National Natural
Science Foundation of China (21871138), and the Natural
Science Foundation of Jiangsu Province (BK20170984).
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