Tetrahedron p. 4047 - 4058 (1981)
Update date:2022-08-05
Topics:
Seebach, Dieter
Pohmakotr, Manat
Conjugated unsaturated carbonyl compounds and their analogues 1 are a1,3,5...-reagents.An umpolung of this intrinsic reactivity can be achieved by generation of the dianions 2, LUMO filled ?-systems, from hydrogenated precursors, see schemes 1
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Doi:10.1016/S0040-4039(00)87368-2
(1982)Doi:10.1007/BF00761543
(1982)Doi:10.1002/cssc.201500700
(2015)Doi:10.1021/ja01176a603
(1949)Doi:10.1021/ol500865j
(2014)Doi:10.1055/s-1982-29842
(1982)