Journal of Organic Chemistry p. 85 - 88 (1984)
Update date:2022-09-26
Topics:
Okuyama, Tadashi
Kawao, Shoji
Fueno, Takayuki
Hydrolysis rates of β-methyl-substituted ketene dithioacetals were measured. β-Monomethyl and β,β-dimethyl substitutions reduced the reactivity of the parent acetal by factors of 26 and 6.7 x 105, respectively.Similar methyl substitutions of trithioorthoacetate, however, enhanced the hydrolysis reactivity by 3 and 23 times.The reversibility of protonation of ketene dithioacetal during hydrolysis was slightly increased by a β-methyl group, but dimethyl substitution seemed to inhibit reversibility by raising the potential barrier to protonation.
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