ACS Catalysis
Letter
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were added to the liquid phase as a solvent and an internal
standard substance for a quantitative analysis, respectively.
Products in liquid and gas phases were analyzed by using a gas
chromatograph equipped with an FID (Shimadzu GC-2014)
and GC/MS (Shimadzu QP2010 Ultra) using a CP-Sil5
(length 50 m, i.d. 0.25 mm, film thickness 0.25 μm) or TC-
WAX (length 30 m, i.d. 0.25 mm, film thickness 0.25 μm)
capillary column.
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ASSOCIATED CONTENT
* Supporting Information
■
S
Details of Tables 1 and 2 (Tables S1 and S2), reported yields
for the synthesis of cyclic carbonates from CO2 and
corresponding alcohols (Table S3), details of Schemes 2 and
3 (Table S4), reported yields of 6-membered ring carbonate
from CO2 and corresponding oxetane (Table S5), catalyst
recycle test (Table S6), effect of calcination temperature of the
catalyst (Figure S1), and the reaction rates of 2-cyanopyridine
hydration (Figure S2) and PC formation (Figure S3). This
material is available free of charge via the Internet at http://
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AUTHOR INFORMATION
Corresponding Author
Notes
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(19) (a) Vivier, L.; Duprez, D. ChemSusChem 2010, 3, 654−678.
(b) Sato, S.; Sato, F.; Gotoh, H.; Yamada, Y. ACS Catal. 2013, 3, 721−
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1397−1405.
(20) Honda, M.; Tamura, M.; Nakagawa, Y.; Sonehara, S.; Suzuki, K.;
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(21) Tamura, M.; Wakasugi, H.; Shimizu, K.; Satsuma, A. Chem.
Eur. J. 2011, 17, 11428−11431.
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
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Part of this research was funded by the Cabinet Office,
Government of Japan through its “Funding Program for Next
Generation World-leading Researchers”.
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