Helvetica Chimica Acta p. 522 - 533 (1983)
Update date:2022-09-26
Topics:
Oppolzer, Wolfgang
Zutterman, Freddy
Baettig, Kurt
(+/-)-α-Acoradiene (4) has been synthesized from 3-methoxy-2-cyclohexenone by a sequence of 8 steps.The key steps (Scheme 6) are the regio- and stereoselective photo<2+2>addition 7 -> 6 and the reductive fragmentation 6 -> 5.
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(2010)