10.1002/anie.201813182
Angewandte Chemie International Edition
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decarboxylation can yield the rhodium species G. Further reductive
elimination and dissociation delivers the final products and
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regenerates the active catalyst. At
a
lower temperature,
decarboxylation can be inhibited from acylrhodium complex F
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In summary, we have reported an efficient C7-selective direct
arylation, olefination, methylation and acylation of indoles with the
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employed commercially available carboxylic acids or anhydrides,
does not require the addition of an exogenous ligand, and is
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Acknowledgments
We thank the NSF of China (Grant 2167020084), Jiangsu provincial
“Innovation
& Entrepreneurship Talents Plan” and Jiangsu
provincial “ Outstanding Youth Funds” for their financial support.
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Keywords: Indoles ·arylation ·olefination ·methylation ·acylation
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