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203 K): ı = 5.50 (m, H1); 5.59 (m, H2); 2.53 (m, H3), 2.08 (m, H3 );
1.69 (m, H4), 1.17 (m, H 4); 1.51 (m, H5); 1.92 (m, H6), 1.17 (m,
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H 12); 1.57 (m, H13), 1.36 (m, H 13); 2.00 (m, H14); 1.33 (m, H15);
3.1 (m, H16) ppm.
MS (70 eV): m/z (%) = 55(12.9), 67(70.9), 80(70.9), 91(30.5),
93(31.1), 107(27.5), 119(7.25), 134(15.8), 147(5.3), 175(100),
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For the mixture of A and B.
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IR (film): ꢀ( C–H st) = 3045 cm−, ꢀ(C–H st) = 2940 cm−,
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C
st) = 1614 cm−, ꢀ(CH2 ı) = 3045 cm−, ꢀ(C–C
3.1.1. Product (3) as a mixture of isomers
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NMR C13 (176 MHz, CDCl3, 203 K): ı = 139.17, 137.79, 135.06,
(d) ppm [6,14].
MS (70 eV): m/z (%) = 44(8.6), 55(15.7), 67(34.4), 79(61.4),
91(57.5), 107(34.0), 119(25.1), 134(100.0), 173(9.9), 175(10.4),
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(m, H12), 1.41 (m, H 12); 1.57 (m, H13), 1.36 (m, H 13); 2.00 (m,
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173(8.4), 187(5.8), 216(20.9) [12,61].
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Acknowledgements
We are grateful to Prof. J.J. Schneider for providing laboratory
facilities.
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This work was supported by the RFBR (Russia) and CRDF (USA)
(The international grant No RUC1-2862-IR-07) and Federal Agency
for Science and Innovations of the Russian Federation (project
#02.512.11.2215).
P.K. thanks DAAD Michail-Lomonosov-Forschungsstipendien
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