Journal of Organic Chemistry p. 4580 - 4582 (1983)
Update date:2022-08-04
Topics:
Schank, K.
Frisch, A.
Zwanenburg, B.
By an independent synthesis the oxidation product of 1,1-dichloro-2,2-dimethyl-1-(phenylthio)-3-butene (1) was shown not to be α-oxo sulfone "2" as published earlier but a phenylsulfonyl γ-butyrolactone, 3.This synthesis involves the intramolecular reaction of a sulfenic carboxylic mixed anhydride with an olefinic bond.A rationale for the formation of 3 from 1 is presented.
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