652
K.-L. Zhang et al. / Polyhedron 28 (2009) 647–652
283 (1999) 1148;
drous while complex 2 is anhydrous shows that some N-containing
compounds, such as pyrazine and pyrazole, may have great influ-
ence on the structure and composition of some MOFs in this sys-
tem, which may partially result from the different intial pH
values of the reaction solutions. A new strategy to design anhy-
drous MOFs may be found through further thoroughly investiga-
tion on how anhydrous complex 2 was formed. In addition, the
solid state photoluminescence properties of the coordination poly-
mers 1 and 2 have been studied.
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Acknowledgments
We gratefully acknowledge the Foundation of Jiangsu Provincial
Key Program of Physical Chemistry in Yangzhou University for the
financial support of this work.
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mentary crystallographic data for 1 and 2. These data can be ob-
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