Carbohydrate Research p. 105 - 120 (1982)
Update date:2022-08-04
Topics:
Tate, Max E.
Ellis, Jeffrey G.
Kerr, Allen
Tempe, Jacques
Murray, Keith E.
Shaw, Kevin J.
The product known as agropine from crown-gall tumour is shown to be indistinguishable in all of its properties ( physical, chemical, and biological) from N2-(1'-deoxy-D-mannitol-1'-yl)-L-glutamine, 1,2'-lactone, a C11H20N2O7 compound produced by cyclisation of N2-(1'-deoxy-D-mannitol-1'-yl)-L-glutamine.Two prior assignments of a C11H17NO7 formula obtained by high-resolution electronimpact mass spectrometry have been shown by field-desorption mass spectrometry to correspond to a fragment produced by the rapid loss of ammonia from the parent molecular species.
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