Tetrahedron p. 1501 - 1510 (1984)
Update date:2022-08-02
Topics:
Katritzky, Alan R.
Kashmiri, M. Akram
Wittmann, Dieter K.
The N-substituents are transferred from the title cations to the C-atom of nitroalkane anions in high yield at 25-80 deg C in DMSO solution.The title cations are readily available from the appropriate pyrylium cations and primary amines of types RCH2NH2 and RR'CHNH2, allowing a general 2-step method for the preparation of higher nitroalkanes.Spectral properties of a variety of nitroalkanes are discussed.
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Doi:10.1016/0022-328X(90)87079-S
(1990)Doi:10.1016/S0040-4039(01)91071-8
(1984)Doi:10.1002/jps.2600721115
(1983)Doi:10.1016/0040-4039(84)80021-0
(1984)Doi:10.1246/bcsj.60.3468
(1987)Doi:10.1246/bcsj.57.1637
(1984)