Journal of Organic Chemistry p. 3094 - 3101 (2017)
Update date:2022-08-03
Topics:
Huang, He
Wu, Yang
Zhang, Wen
Feng, Chun
Wang, Bi-Qin
Cai, Wan-Fei
Hu, Ping
Zhao, Ke-Qing
Xiang, Shi-Kai
Copper-catalyzed regioselective C-H sulfonyloxylation of electron-rich arenes with p-toluenesulfonic acid has been developed. Electron-rich benzene derivatives and heteroarenes can undergo this C-H sulfonyloxylation reaction to generate aryl tosylates. Furthermore, sulfonyloxylation of aryl(mesityl)iodonium sulfonates has also been investigated. Both aryl(mesityl)iodonium tosylates and triflates can react smoothly to get aryl sulfonates. The formed aryl sulfonates can be converted to phenols, as well as used as good partners of cross-coupling reactions.
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