10.1002/cctc.201801098
ChemCatChem
FULL PAPER
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atomic (111) surface layers (lattice constants a = b = 11.5 Å, 81
atoms) unless otherwise noted. The slab was separated by a
vacuum space with a height of 20 Å. All atoms except the oxygen
atoms in the bottom layer were fully relaxed.
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This work was supported by the KAKENHI grants JP18K14051,
JP17H01341, JP24109014, JP15K13710, JP17H03117, and
JP15K05431 from the Japan Society for the Promotion of
Science (JSPS), by the Japanese Ministry of Education, Culture,
Sports, Science, and Technology (MEXT) within the projects
"Integrated Research Consortium on Chemical Sciences
(IRCCS)" and "Elements Strategy Initiative to Form Core
Research Center", as well as by the JST-CREST project
JPMJCR15P5, JPMJCR15P4, and JPMJCR17J3. The authors
are indebted to the technical division of the Institute for Catalysis
(Hokkaido University) for the manufacturing of experimental
equipment.
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Keywords: Amide alcoholysis • C–N bond cleavage • CeO2 •
Acid and base cooperation
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