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ASSOCIATED CONTENT
Supporting Information.
Experimental procedures, characterization data and relevant NMR
spectra can be found in the Supporting Information available free
DOI:
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AUTHOR INFORMATION
Corresponding Author
* Tim.claridge@chem.ox.ac.uk
* Stephen.fletcher@chem.ox.ac.uk
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Soc. 2008, 130, 12862.
Funding Sources
We are grateful to the EPSRC for financial support in the form of
a Career Acceleration Fellowship to SPF (EP/H003711/1) and a
Standard Grant (EP/N022246/1).
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ACKNOWLEDGMENT
The authors acknowledge Dr Barbara Odell for initial assistance
in NMR.
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ABBREVIATIONS
AAA, Asymmetric Allylic Alkylation; NHC, Nꢀheterocyclic
Carbene; DMS, Dimethyl sulfoxide; TBAI, Tetrabutylammonium
iodide; TMSI, Iodotrimethylsilane; DYKAT, Dynamic Kinetic
Asymmetric Transformation; DET, direct enantioꢀconvergent
transformation.
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