T.W. Graham et al. / Journal of Organometallic Chemistry 692 (2007) 4481–4485
4485
(l2-Me)(l2-NPi-Pr3)(l4-C)(AlMe2)3 occurs on the periphery
of the molecule. This demonstrates the robust nature and
stability of the TiCAl3 core of these TiAl3-carbide species.
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Acknowledgments
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Financial support from NSERC of Canada and NOVA
Chemicals Corporation is gratefully acknowledged.
[17] J.F. Hartwig, Angew. Chem., Int. Ed. 37 (1998) 2046–2067.
[18] M. Kawatsura, J.F. Hartwig, J. Am. Chem. Soc. 121 (1999) 1473–
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Appendix A. Supplementary material
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CCDC 636038 and 636039 contain the supplementary
crystallographic data for 1 and 2. The data can be obtained
Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK;
fax: (+44) 1223-336-033; or e-mail: deposit@ccdc.cam.
ac.uk. Supplementary data associated with this article can
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